chemistry / Organic Chemistry / free

Stereochemistry

Rotate molecules in space and see why mirror-image arrangements can behave differently.

Follow the cause1 / 3

Connectivity fixes the atom graph. The same bonds can still allow more than one three-dimensional arrangement.

molecules in 3Dchirality · S arrangement
Focus the idea
Three-dimensional arrangement can change molecular behaviourA tetrahedral centre in the S arrangement is viewed at a rotation of 32 degrees; rotating it never changes that configuration, while reflecting it gives the mirror-image enantiomer.C*mirror pairsame atoms ≠ same 3-D effect
connectivitysame
arrangementS
rotation32°
propertyselective

Rotate the centre as far as you like: a rotation changes the view, never the configuration. Only reflecting the molecule produces its non-superimposable enantiomer.

The stage uses a tetrahedral centre as a spatial cue. Assigning R/S in a real molecule requires priority rules and a defined viewing orientation; rotation alone is not a full assignment procedure.

04 / PRACTICE

Make the chemistry yours.

0 / 3 checked

Answer from the model, then use the explanation to connect the particle picture to the chemical rule.

CHECK 1 / 3

What makes enantiomers distinct?